Nagendra Udupa, K. ; Sarkar, Sabyasachi (1985) Synthesis of the dicyanopentasulfidonickelate(II) anion Journal of Organometallic Chemistry, 284 (2). C36-C38. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0022-328X(85)87222-3
Abstract
Potassium tetracyanonickelate reacts with elemental sulfur and KOH in DMF to give the [(NC)2NiS5]2− anion, which has been isolated as its PPh4+ and AsPh4+ salts. The XPS S(2p) binding energies of the S5 ring sulfur are in the ratio 2(162.8 eV)/3(163.6 eV). Cyclic voltammetry shows that the compound undergoes an irreversible reduction at −1.825 V.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 59318 |
| Deposited On: | 06 Sep 2011 06:07 |
| Last Modified: | 06 Sep 2011 06:07 |
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