Studies in sesquiterpenes-XXII: Structure of mustakone and copaene

Kapadia, V. H. ; Nagasampagi, B. A. ; Naik, V. G. ; Sukh Dev, (1965) Studies in sesquiterpenes-XXII: Structure of mustakone and copaene Tetrahedron, 21 (2). pp. 607-618. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4020(01)82231-6

Abstract

In connection with the structure determination of mustakone, a sesquiterpene ketone from Cyperus rotundus Linn., it became apparent that the currently accepted structure of copaene, a tricyclic sesquiterpene hydrocarbon, first, isolated in 1914, was untenable. Evidence is now presented which permits the derivation of the absolute stereostructures of copaene and mustakone.

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