Rajan, V. P. ; Bannore, S. N. ; Subbarao, H. N. ; Sukh Dev, (1984) Ligand effect in epoxidatidns by hydroperoxides using molybdenum catalyst: epox idation of 3-carene Tetrahedron, 40 (6). pp. 983-990. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)91235-9
Abstract
Epoxidation of (+)-3-carene with pinane hydroperoxide in presence of various transition metal catalysts, has been evaluated as a preparative method for (+)-3α,4α-epoxycarane. Catalysts based on Mo(VI) were found to be most suitable. A distinct ligand effect was noted for this oxidation and a plausible rationale is put forward.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 59173 |
| Deposited On: | 03 Sep 2011 11:48 |
| Last Modified: | 03 Sep 2011 11:48 |
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