Yadav, J. S. ; Subba Reddy, B. V. ; Borkar, Prashant ; Janardhan Reddy, P. (2009) Addition of aryl cuprates to azides: a novel approach for the synthesis of unsymmetrical diaryl amines Tetrahedron Letters, 50 (48). pp. 6642-6645. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2009.09.056
Abstract
Aryl and benzyl azides react smoothly with aryl cuprates, generated in situ from aryl magnesium bromide and CuCN in THF to furnish a variety of unsymmetrical diaryl amines in good yields. This is the first report on the synthesis of diarylamines from aryl azides and aryl bromides via an organometallic approach.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Aryl Azides; Grignard Reaction; Aryl Cuprates; Diaryl Amines |
| ID Code: | 58956 |
| Deposited On: | 02 Sep 2011 03:36 |
| Last Modified: | 02 Sep 2011 03:36 |
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