Stereoselective total synthesis of (−)-pyrenophorol

Yadav, J. S. ; Subba Reddy, U. V. ; Subba Reddy, B. V. (2009) Stereoselective total synthesis of (−)-pyrenophorol Tetrahedron Letters, 50 (44). pp. 5984-5986. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2009.07.047

Abstract

An efficient stereoselective total synthesis of (−)-pyrenophorol 1 is described. The key steps involved in this synthesis are hydrolytic kinetic resolution (HKR), MacMillan α-hydroxylation, Horner-Wadsworth-Emmons (HWE) reaction, and Mitsunobu cyclization.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Macrodiolide; Pyrenophorol; Hydrolytic Kinetic Resolution (HKR); Macmillan α-hydroxylation; Horner-Wadsworth-Emmons Reaction; Mitsunobu Cyclization
ID Code:58953
Deposited On:02 Sep 2011 03:36
Last Modified:02 Sep 2011 03:36

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