Free radical addition of haloalkanes to polymer bound olefins and its application to the solid-phase synthesis of pyrethroids

Kumar, H. M. S. ; Pawan Chakravarthy, P. ; Shesha Rao, M. ; Sunder Ram Reddy, P. ; Yadav, J. S. (2002) Free radical addition of haloalkanes to polymer bound olefins and its application to the solid-phase synthesis of pyrethroids Tetrahedron Letters, 43 (43). pp. 7817-7819. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(02)01609-X

Abstract

Polymer bound olefins undergo free radical initiated 1,2-addition when reacted with a variety of haloalkanes. The strategy could be applied successfully to the solid-phase synthesis of dihaloethenylcyclopropane carboxylic acids which are the key fragments of synthetic pyrethroids.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Solid Phase; Radical Addition; Pyrethroids
ID Code:58917
Deposited On:02 Sep 2011 03:15
Last Modified:02 Sep 2011 03:15

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