Yadav, J. S. ; Subba Reddy, B. V. ; Narasimha Chary, D. ; Chandrakanth, D. (2009) InX3-catalyzed haloamidation of vinyl arenes: a facile synthesis of α-bromo- and α-fluoroamides Tetrahedron Letters, 50 (10). pp. 1136-1138. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2008.12.090
Abstract
A variety of alkenes are converted into the corresponding α-fluoroamides in high yields by selectfluorTM in the presence of 10 mol % of InF3 in nitrile solution. α-Bromoamides are obtained with NBS in the presence of 10 mol % InBr3 under similar conditions. The use of Lewis acid in haloamidation significantly improved the yields and reaction rates.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Indium(III) Halides; Vinyl Arenes; Haloamidation; α-Fluoroamides |
| ID Code: | 58898 |
| Deposited On: | 02 Sep 2011 03:33 |
| Last Modified: | 02 Sep 2011 03:33 |
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