Subba Reddy, B. V. ; Ganesh, A. V. ; Siva Krishna, A. ; Narayana Kumar, G. G. K. S. ; Yadav, J. S. (2011) Sc(OTf)3-catalyzed sugar based tandem ene-Prins cyclization: a novel synthesis of hexahydro-2H-furo[3,2-b]pyranopyran scaffolds Tetrahedron Letters, 52 (26). pp. 3342-3344. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2011.04.077
Abstract
Ttandem ene-Prins cyclization between an aldehyde and an olefin tethered sugar aldehyde has been achieved using a catalytic amount of scandium triflate (10 mol %) at ambient temperature to give a novel series of sugar annulated pyranopyran derivatives in good yields with high selectivity. This is the first report on sugar based ene-Prins cyclization between an aldehyde and O-prenyl derivative of a sugar aldehyde.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | D-glucose; Ene-Prins Cyclization; Sugar Annulated Heterocycles; Metal Triflate |
| ID Code: | 58881 |
| Deposited On: | 02 Sep 2011 03:43 |
| Last Modified: | 02 Sep 2011 03:43 |
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