A new entry to the stereocontrolled synthesis of CD rings of Taxol

Yadav, J. S. ; Sasmal, Pradip K. (1997) A new entry to the stereocontrolled synthesis of CD rings of Taxol Tetrahedron Letters, 38 (50). pp. 8769-8772. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(97)10347-1

Abstract

Stereocontrolled synthesis of the highly functionalized CD subunit of Taxol utilizing Diels-Alder reaction, Baeyer-Villiger oxidation of bridged keto system, stereodirected hydroboration using thexylborane and stereoselective Sharpless allylic hydroxylation as the key steps is described. Facile and stereocontrolled synthesis of highly functionalized CD ring derivatives of Taxol is reported.

Item Type:Article
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ID Code:58872
Deposited On:02 Sep 2011 03:09
Last Modified:02 Sep 2011 03:09

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