1,4-Conjugate addition of allyltrimethylsilane to α,β-unsaturated ketones

Yadav, J. S. ; Reddy, B. V. S. ; Sadasiv, K. ; Satheesh, G. (2002) 1,4-Conjugate addition of allyltrimethylsilane to α,β-unsaturated ketones Tetrahedron Letters, 43 (52). pp. 9695-9697. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(02)02373-0

Abstract

α,β-Unsaturated ketones smoothly undergo conjugate addition with allyltrimethylsilane in the presence of a catalytic amount of elemental iodine under very mild and convenient conditions to afford the corresponding Michael adducts in high yields with high selectivity.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Michael Addition; α,β-unsaturated Ketones; Iodine Catalysis; 1,4-adducts
ID Code:58866
Deposited On:02 Sep 2011 03:15
Last Modified:02 Sep 2011 03:15

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