Sabitha, Gowravaram ; Siva Sankara Reddy, S. ; Yadav, J. S. (2011) Stereoselective total synthesis of cryptopyranmoscatone A1 Tetrahedron Letters, 52 (18). pp. 2407-2409. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2011.02.107
Abstract
The first total synthesis of cryptopyranmoscatone A1 isolated from Cryptocarya moschata has been accomplished from 3,4,6-tri-O-acetyl-D-glucal. In addition to the RCM and cross-metathesis (CM) reactions, the synthesis features a highly diastereoselective Brown's allylation reaction and sets the absolute stereochemistry of the natural product.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Cryptopyranmoscatone; Oxa-Michael; 3,4,6-tri-O-acetyl-D-glucal; Cross-metathesis; Brown's Allylation; RCM |
| ID Code: | 58808 |
| Deposited On: | 02 Sep 2011 03:42 |
| Last Modified: | 02 Sep 2011 03:42 |
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