Total synthesis of cryptopyranmoscatone B1 from 3,4,6-tri-O-acetyl-D-glucal

Sabitha, Gowravaram ; Siva Sankara Reddy, S. ; Yadav, J. S. (2010) Total synthesis of cryptopyranmoscatone B1 from 3,4,6-tri-O-acetyl-D-glucal Tetrahedron Letters, 51 (48). pp. 6259-6261. ISSN 0040-4039

Full text not available from this repository.

Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2010.09.085

Abstract

The first stereoselective total synthesis of the natural cryptopyranmoscatone B1 has been accomplished from 3,4,6-tri-O-acetyl-D-glucal. In addition to the double cross-metathesis reaction, a tandem nucleophilic addition-diastereoselective reduction of an in situ generated oxocarbenium cation have been used as key steps to assemble the glycoside moiety of the target molecule.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Cryptopyranmoscatone; Styryllactone; 3,4,6-tri-O-acetyl-D-glucal; Cross-metathesis; β-C-glycoside
ID Code:58807
Deposited On:02 Sep 2011 03:42
Last Modified:02 Sep 2011 03:42

Repository Staff Only: item control page