Yadav, J. S. ; Subba Reddy, B. V. ; Satheesh, G. ; Narasimhulu, G. ; Portier, Y. ; Madhavi, C. ; Kunwar, A. C. (2008) A novel biomimetic condensation of 2-deoxyribose, aryl amine and acetyl acetone to bicyclic aminols catalyzed by InCl3 Tetrahedron Letters, 49 (20). pp. 3341-3345. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2008.02.080
Abstract
2-Deoxyribose, an aryl amine and acetyl acetone undergo smooth cyclocondensation in the presence of 10 mol % of InCl3 under mild conditions to afford the corresponding sugar-derived bicyclic aminols in good yields with moderate diastereoselectivity. This reaction is reminiscent of the celebrated tropinone synthesis of Robinson. The structures of the products are established by using various NMR experiments and X-ray crystallographic studies.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | 2-deoxysugars; Indium Trichloride; Aryl Amines; Heterobicycles |
| ID Code: | 58781 |
| Deposited On: | 02 Sep 2011 03:30 |
| Last Modified: | 02 Sep 2011 03:30 |
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