Yadav, J. S. ; Vidyanand, D. ; Rajagopal, D. (1993) Stereoselective synthesis of D(+)-erythro and L(−)-threo sphingosines from carbohydrates Tetrahedron Letters, 34 (7). pp. 1191-1194. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4039(00)77525-3
Abstract
Stereocontrolled syntheses of D(+)-erythro and L(−)-threo sphingosines are described starting from D-xylose and D-arabinose respectively through acetylenic intermediates 3 and 4, obtained by base induced double elimination of the β-alkoxy chlorides 5 & 13. Synthesis of the title compounds are described.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | D(+)-erythro and L(−)-threo Sphingosines; Base Induced Double Elimination Reaction; Acetylenic Alcohol |
| ID Code: | 58773 |
| Deposited On: | 02 Sep 2011 03:08 |
| Last Modified: | 02 Sep 2011 03:08 |
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