The stereoselective total synthesis of (−)-cleistenolide

Subba Reddy, B. V. ; Phaneendra Reddy, B. ; Pandurangam, T. ; Yadav, J. S. (2011) The stereoselective total synthesis of (−)-cleistenolide Tetrahedron Letters, 52 (18). pp. 2306-2308. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2011.02.025

Abstract

The stereoselective total synthesis of (−)-cleistenolide is described employing the Barbier allylation, MacMillan α-hydroxylation, Stille-Gennari olefination, and CeCl3·7H2O mediated lactonization as key steps.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Cleistenolide; α,β-unsaturated-δ-lactones; Macmillan α-hydroxylation; Stille-Gennari Reaction
ID Code:58769
Deposited On:02 Sep 2011 03:42
Last Modified:02 Sep 2011 03:42

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