Stereoselective synthesis of (+)-cryptocarya diacetate by an iterative Prins cyclisation and reductive cleavage sequence

Yadav, J. S. ; Purushothama Rao, P. ; Sridhar Reddy, M. ; Venkateswar Rao, N. ; Prasad, A. R. (2007) Stereoselective synthesis of (+)-cryptocarya diacetate by an iterative Prins cyclisation and reductive cleavage sequence Tetrahedron Letters, 48 (8). pp. 1469-1471. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2006.12.068

Abstract

A highly stereoselective synthesis of (+)-cryptocarya diacetate is achieved through our recently developed strategy for the construction of 1,3-diols via Prins cyclisation. The route relies mainly on the reductive cleavage of allylic ethers, ozonolysis and Wittig olefination along with Prins cyclisation.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Prins Cyclisation; Reductive Cleavage; 1,3-diol; Ozonolysis
ID Code:58753
Deposited On:02 Sep 2011 03:25
Last Modified:02 Sep 2011 03:25

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