A highly efficient practical method for the synthesis of chiral polyhydroxy-(E,E)-1-chlorodienols and (E)-5-hydroxy enynes

Yadav, J. S. ; Barma, D. K. ; Dutta, Dinah (1997) A highly efficient practical method for the synthesis of chiral polyhydroxy-(E,E)-1-chlorodienols and (E)-5-hydroxy enynes Tetrahedron Letters, 38 (25). pp. 4479-4482. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(97)00907-6

Abstract

An efficient protocol for the synthesis of chiral polyhydroxy-(E,E)-1-chlorodienols and (E)-5-hydroxy enynes from chiral 4,5-epoxy trans allyl chlorides and 4,5-O-isopropylidene allyl chlorides is described by using stoichiometric amount of LiNH2 or LDA in HMPA:THF (1:5) useful in the synthesis of biologically active natural products.

Item Type:Article
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ID Code:58740
Deposited On:02 Sep 2011 03:09
Last Modified:02 Sep 2011 03:09

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