Montmorillonite KSF clay catalyzed one-pot synthesis of α-aminonitriles

Yadav, J. S. ; Subba Reddy, B. V. ; Eeshwaraiah, B. ; Srinivas, M. (2004) Montmorillonite KSF clay catalyzed one-pot synthesis of α-aminonitriles Tetrahedron, 60 (8). pp. 1767-1771. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tet.2003.12.043

Abstract

Aryl imines, formed in situ from aldehydes and amines undergo smoothly nucleophilic addition with trimethylsilyl cyanide on the surface of montmorillonite KSF clay under mild reaction conditions to afford the corresponding α-aminonitriles in excellent yields. The solid acid can be recovered and recycled in subsequent reactions with a gradual decrease of activity.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Solid Acids; Aryl Imines; Trimethylsiyl Cyanide; α-aminonitriles
ID Code:58736
Deposited On:02 Sep 2011 03:18
Last Modified:02 Sep 2011 03:18

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