Synthesis and structural characterization of [α,α'-bis{bis(2-(diphenylphosphino)ethyl)amino}ethane] bis(tetrahydroborato)dicopper(I). Hydrogen bridge attachment of the tetrahydroborate group

Taqui Khan, M. M. ; Paul, Parimal ; Venkatasubramanian, K. (1991) Synthesis and structural characterization of [α,α'-bis{bis(2-(diphenylphosphino)ethyl)amino}ethane] bis(tetrahydroborato)dicopper(I). Hydrogen bridge attachment of the tetrahydroborate group Polyhedron, 10 (15). pp. 1827-1829. ISSN 0277-5387

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0277-5387(00)83806-1

Abstract

The synthesis and structural characterization of [α,α'-bis{bis(2-(diphenylphosphino)ethyl)amino}ethane]bis(tetrahydroborato)dicopper(I) complex is reported. Crystal structure analysis shows that each copper atom possesses a distorted tetrahedral geometry with ligation to two phosphorus atoms of the ligand and two hydrogen atoms of BH4. 1H, 13C, 31P and 11B NMR and IR data are also presented.

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Deposited On:31 Aug 2011 12:21
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