Taqui Khan, M. M. ; Srinivas Mohan, M. (1974) Kinetics of adenosine-5'-triphosphate hydrolysis Journal of Inorganic and Nuclear Chemistry, 36 (3). pp. 707-709. ISSN 0022-1902
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0022-1902(74)80138-7
Abstract
The kinetics of the nonenzymic hydrolysis of adenosine-5'-triphosphate[ATP] in aqueous solutions has been studied at 56·0° and 64·0°, over a broad pH range 3·0-9·0, and μ=0·1 (KNO3). The reaction was followed by measuring calorimetrically the inorganic orthosphosphate liberated according to the overall reaction ATP + H2O → ADP + Pi. pH-rate profiles have been analysed and the overall rate constants have been resolved into individual rate constants relating to the various ionic species in solution. Thermodynamic activation parameters, ΔH≠, ΔS≠, and ΔF≠, for the specific rate constants of the various ionic species are reported.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 58545 |
| Deposited On: | 31 Aug 2011 12:13 |
| Last Modified: | 31 Aug 2011 12:13 |
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