Taqui Khan, M. M. ; Ramachandraiah, G. ; Mehta, S. H. ; Abdi, S. H. R. ; Kumar, Sanal (1990) Mononuclear bis(dimethylglyoximato)ruthenium(III) complexes with different appended axial groups: highly efficient catalysts for water oxidation Journal of Molecular Catalysis, 58 (2). pp. 199-203. ISSN 0304-5102
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0304-5102(90)85039-K
Abstract
Mononuclear ruthenium(III) complexes [Ru(H-dmg)2XY]n (n=−1, when X=Y=Cl− or ClO4−n=0 when X=Cl− and Y = imidazole or 2-methylimidazole) were used as catalysts in water oxidation to molecular oxygen by electrolytic and chemical methods. The evolved oxygen in both methods was measured at atmospheric pressure (30°C) using a specially-designed gas volumetric apparatus. The maximum turnover number of the above complexes (mol O2 evolved per mole complex per hour) are reported.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 58531 |
| Deposited On: | 31 Aug 2011 12:18 |
| Last Modified: | 31 Aug 2011 12:18 |
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