Taqui Khan, M. M. ; Chatterjee, Debabrata ; Merchant, R. R. ; Bhatt, Anjani ; Sanal, Kumar S. (1991) Synthesis of the complex [RuV=O(edta)]− and its application in the oxidation of saturated substrates by oxygen atom transfer reaction Journal of Molecular Catalysis, 66 (3). pp. 289-293. ISSN 0304-5102
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0304-5102(91)80021-T
Abstract
Oxidation of cyclohexane and cyclohexanol with Ru(edta)(O)− was studied spectrophotometrically by following the disappearance of the oxo peak of the complex RuV(edta)(O)− at constant pH 5.0. The reaction rate was found to be first order with respect to oxo complex. The rate of oxidation increases with increasing substrate concentration and reaches a limit at high substrate concentration. Rate and activation parameters are in accordance with the mechanism proposed for the oxygen atom transfer reaction from high-valent RuV(edta)(O)− complexes to saturated hydrocarbons.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 58504 |
| Deposited On: | 31 Aug 2011 12:21 |
| Last Modified: | 31 Aug 2011 12:21 |
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