Synthesis of (-)-coniine and (-)-pipecoline using ruthenium catalyzed ring closing metathesis

Pachamuthu, Kandasamy ; Vankar, Yashwant D. (2001) Synthesis of (-)-coniine and (-)-pipecoline using ruthenium catalyzed ring closing metathesis Journal of Organometallic Chemistry, 624 (1-2). pp. 359-363. ISSN 0022-328X

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0022-328X(00)00930-X

Abstract

Ring closing metathesis employing the well-known Grubbs' ruthenium catalyst has been used as the key step in the synthesis of piperidine alkaloids, (-)-coniine and (-)-pipecoline, and the asymmetric induction has been performed by using (R)-α-methyl benzylamine as an auxiliary.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Grubbs' Ruthenium Catalyst; Ring Closing Metathesis; Synthesis; Piperidine Alkaloids; (R)-α-methyl Benzylamine
ID Code:58308
Deposited On:31 Aug 2011 06:36
Last Modified:31 Aug 2011 06:36

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