Do the electronic effects of sulfur indeed control the π-selectivity of γ-sulfenyl enones? An investigation

Yadav, Veejendra K. ; Ganesh Babu, K. ; Parvez, Masood (2004) Do the electronic effects of sulfur indeed control the π-selectivity of γ-sulfenyl enones? An investigation Journal of Organic Chemistry, 69 (11). pp. 3866-3874. ISSN 0022-3263

Full text not available from this repository.

Official URL: http://pubs.acs.org/doi/abs/10.1021/jo034608c

Related URL: http://dx.doi.org/10.1021/jo034608c

Abstract

The electronic effects of sulfur in γ-sulfenyl enones are not transmitted to the carbonyl carbon through the π bond as reported previously. The diastereoselectivity is rather controlled by a combination of several other factors. The steric effects arising from the substituents on the sulfur atom and the γ-carbon and the bulk of the nucleophile constitute the major control elements.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:58254
Deposited On:31 Aug 2011 06:56
Last Modified:31 Aug 2011 06:56

Repository Staff Only: item control page