Yadav, Veejendra K. ; Gupta, Archana (2009) Reaction of 2-silylmethylcyclopropyl ketones with in situ oxirane-derived aldehydes and formation of 2-hydroxymethyl tetrahydrofurans Tetrahedron Letters, 50 (32). pp. 4647-4650. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2009.05.107
Abstract
The enolates formed from Lewis acid treatment of (2-trimethylsilylmethyl)cyclopropyl alkyl and aryl ketones reacted with aldehydes formed in situ from alkoxy-, aryl- and vinyl-substituted oxiranes to generate aldol products in good yields. Selected aldol products were conveniently transformed into highly substituted tetrahydrofurans under oxidative conditions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | (2-Trimethylsilylmethyl)cyclopropyl Ketone; Oxirane; Aldol; Oxidative Ring Closure; 2-Hydroxymethyl Tetrahydrofuran |
| ID Code: | 58251 |
| Deposited On: | 31 Aug 2011 06:57 |
| Last Modified: | 31 Aug 2011 06:57 |
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