Investigation of the diastereoselectivity of tricyclo (5.2. 1.02, 6) decan-10-ones: controversies and agreements

Yadav, Veejendra K. ; Singh, Latika (2005) Investigation of the diastereoselectivity of tricyclo (5.2. 1.02, 6) decan-10-ones: controversies and agreements Journal of Organic Chemistry, 70 (2). pp. 692-695. ISSN 0022-3263

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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo048878m

Related URL: http://dx.doi.org/10.1021/jo048878m

Abstract

The diastereoselectivities of tricyclo(5.2.1.02,6)decan-10-one and its derivatives are controlled by antiperiplanar and vicinal σ→πC=O interactions rather than the hyperconjugation effects as reported previously.

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ID Code:58245
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Last Modified:31 Aug 2011 06:56

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