Yadav, Veejendra K. ; Sriramurthy, Vardhineedi (2004) Formal [3+ 2] and [3+ 3] additions of acceptor-substituted cyclopropylmethylsilanes to allenylsilanes Organic Letters, 6 (24). pp. 4495-4498. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol047991w
Related URL: http://dx.doi.org/10.1021/ol047991w
Abstract
1,3-Dipolar synthons formed from vicinal TBDPS-substituted cyclopropyl alkyl/phenyl ketones on treatment with Lewis acids such as TiCl4 and Et2AlCl reacted with allenylsilanes to furnish [3 + 2] and [3 + 3] adducts with high regio- and stereocontrol.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 58221 |
| Deposited On: | 31 Aug 2011 06:56 |
| Last Modified: | 31 Aug 2011 06:56 |
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