Mercuric triflate catalyzed hydroxylative carbocyclization of 1, 6-enynes

Nishizawa, Mugio ; Yadav, Veejendra K. ; Skwarczynski, Mariusz ; Takao, Hiroko ; Imagawa, Hiroshi ; Sugihara, Takumichi (2003) Mercuric triflate catalyzed hydroxylative carbocyclization of 1, 6-enynes Organic Letters, 5 (10). pp. 1609-1611. ISSN 1523-7060

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol034201u

Related URL: http://dx.doi.org/10.1021/ol034201u

Abstract

Hg(OTf)2 exhibits remarkable catalytic activity for the hydroxylative cyclization of 1,6-enynes. The present procedure should involve a sequence of mercuration of a terminal alkyne, carbocyclization, hydration, and protodemercuration that regenerates the catalyst.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:58205
Deposited On:31 Aug 2011 06:55
Last Modified:31 Aug 2011 06:55

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