Palladium catalysed regio and stereoselective reduction of Baylis-Hillman coupling products derived allylic acetates

Pachamuthu, Kandaswamy ; Vankar, Yashwant D. (1998) Palladium catalysed regio and stereoselective reduction of Baylis-Hillman coupling products derived allylic acetates Tetrahedron Letters, 39 (30). pp. 5439-5442. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(98)01049-1

Abstract

Acetates derived from a variety of the Baylis-Hillman products undergo reduction with HCOOH in the presence of Et3N, Pd(OAc)2, and dppe (or tri-isopropylphosphite) to yield the corresponding trisubstituted Z-olefins in good yields displaying high regio and stereoselectivity.

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