Synthesis of 1,4-dideoxy-1,4-iminoheptitol and 1,5-dideoxy-1,5-iminooctitols from D-xylose

Kumar, Amit ; Alam, Mohammed Abrar ; Rani, Shikha ; Vankar, Yashwant D. (2010) Synthesis of 1,4-dideoxy-1,4-iminoheptitol and 1,5-dideoxy-1,5-iminooctitols from D-xylose Carbohydrate Research, 345 (9). pp. 1142-1148. ISSN 0008-6215

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.carres.2010.04.016

Abstract

The synthesis of iminosugars from inexpensive D-xylose in high yields has been developed. The key step in this synthesis involves Wittig olefination or chelation-controlled attack of Grignard reagents on lactol and ring-closing metathesis using first or second generation Grubbs' catalysts.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Iminosugars; Lactol; Wittig Olefination; Ring Closing Metathesis; Dihydroxylation; D-Xylose
ID Code:58188
Deposited On:31 Aug 2011 06:42
Last Modified:31 Aug 2011 06:42

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