A novel three-component reaction of triphenylphosphine, DMAD, and electron-deficient styrenes: facile synthesis of cyclopentenyl phosphoranes

Nair, Vijay ; Deepthi, Ani ; Beneesh, P. B. ; Eringathodi, Suresh (2006) A novel three-component reaction of triphenylphosphine, DMAD, and electron-deficient styrenes: facile synthesis of cyclopentenyl phosphoranes Synthesis, 2006 (9). pp. 1443-1446. ISSN 0039-7881

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Official URL: https://www.thieme-connect.com/ejournals/abstract/...

Related URL: http://dx.doi.org/10.1055/s-2006-926423

Abstract

The zwitterion formed from triphenylphosphine and DMAD adds to electron-deficient styrenes to form stable cyclopentenyl phosphoranes. This is the first example of such a zwitterion in which the phosphine is incorporated into the product.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Triphenylphosphine; Dimethyl Acetylenedicarboxylate; Zwitterions; Electron-deficient Styrenes; Phosphoranes
ID Code:58054
Deposited On:31 Aug 2011 12:47
Last Modified:31 Aug 2011 12:47

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