Nair, Vijay ; George, Tesmol G. ; Augustine, Anu ; Nair, Latha G. (2000) Cerium(IV) ammonium nitrate mediated thiocyanation of dienes: some interesting observations Research on Chemical Intermediates, 26 (9). pp. 923-929. ISSN 0922-6168
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Official URL: http://www.springerlink.com/content/j13kn72j731654...
Related URL: http://dx.doi.org/10.1163/156856700X00408
Abstract
Various 1,3-dienes when treated with a solution of cerium(IV) ammonium nitrate and ammonium thiocyanate in acetonitrile afforded the isothiocyanatothiocyanates via a [3,3] sigmatropic rearrangement. Electron rich dienes afforded the γ-thiocyanato-α,β-unsaturated carbonyl compounds under similar experimental conditions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer. |
| ID Code: | 58035 |
| Deposited On: | 31 Aug 2011 12:43 |
| Last Modified: | 31 Aug 2011 12:43 |
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