Photochemical di-π-methane rearrangement of quinoxalinobarrelenes

Nair, Vijay ; Anilkumar, Gopinathan ; Prabhakaran, Jaya ; Maliakal, Davis ; Eigendorf, Guenter K. ; Williard, Paul G. (1997) Photochemical di-π-methane rearrangement of quinoxalinobarrelenes Journal of Photochemistry and Photobiology A: Chemistry, 111 (1-3). pp. 57-59. ISSN 1010-6030

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Quinoxalinobarrelene 1 underwent facile di-π-methane rearrangement when irradiated in cyclohexane at 250 nm to afford quinoxalinose-mibullvalene 2 in 94% yield. Similar rearrangement was observed with 3 leading to the corresponding semibullvalene 4.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Quinoxalinobarrelene; Di-π-methane Rearrangement; Quinoxalinosemibullvalene
ID Code:58027
Deposited On:31 Aug 2011 12:43
Last Modified:31 Aug 2011 12:43

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