Thermoelectric power in the normal state of Chevrel-phase superconductors of the type Cu1.8Mo6S8-ySey, 0≤y≤8, and Cu1.8Mo6S8-yTey, 0≤y≤4

Rao, V. Vasudeva ; Rangarajan, G. ; Srinivasan, R. (1984) Thermoelectric power in the normal state of Chevrel-phase superconductors of the type Cu1.8Mo6S8-ySey, 0≤y≤8, and Cu1.8Mo6S8-yTey, 0≤y≤4 Journal of Physics F - Metal Physics, 14 (4). pp. 973-980. ISSN 0305-4608

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Official URL: http://iopscience.iop.org/0305-4608/14/4/020

Related URL: http://dx.doi.org/10.1088/0305-4608/14/4/020

Abstract

The thermoelectric power, S, of Chevrel-phase superconductors of the type Cu1.8Mo6S8-ySey, 0<y<8, and Cu1.8Mo6S8-yTey, 0<y<4, have been measured between 300K and the superconducting transition temperature. The high-temperature values are found to arise mainly from the diffusion of conduction electrons while at low temperatures phonon-drag contributions are also observed. The diffusion thermopower is interpreted in terms of Mott-Wilson theory and band-structure data. The phonon specific heat has also been measured in the case of Cu1.8Mo6S8 and Cu1.8Mo6S1Se7 and is shown to be proportional to the phonon-drag part of the thermopower.

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