XPS study of glassy Pd80Ge20

Budhani, R. C. ; Banerjee, A. ; Goel, T. C. ; Chopra, K. L. (1983) XPS study of glassy Pd80Ge20 Journal of Non Crystalline Solids, 55 (1). pp. 93-102. ISSN 0022-3093

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002230...

Related URL: http://dx.doi.org/10.1016/0022-3093(83)90009-1


An X-ray photoemission and Auger electron spectroscopy study of the electronic structure of Pd80Ge20 alloy in its glassy and crystalline states is reported. The glassy state shows some modifications in the valence band structure, symmetry of the Pd 3d3/2-3d3/2spin-orbit doublet and a shift in M45-V-V Auger transition of Pd. Analysis of the chemical shifts in the core-level binding energies of the constituents indicates negligible charge transfer from the metalloid atom (Ge) to d-band of the Pd.

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Deposited On:19 Oct 2010 11:38
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