Santikary, P. ; Yashonath, S. (1996) Deviation from Arrhenius behaviour of rate of intercage diffusion in zeolite Y Electronic Journal of Theoretical Chemistry, 1 (1). pp. 87-92. ISSN 1082-4928
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/ejtc.15...
Related URL: http://dx.doi.org/10.1002/ejtc.15
Abstract
Rate of intercage diffusion (kc) along with rate of cage visits (kv) and diffusion coefficient (D) of sorbates in zeolite Y have been calculated. We show that as a consequence of the dependence of rate of intercage diffusion on short-time behaviour, significant deviation from the Arrhenius behaviour at suffciently high temperatures occurs.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Diffusion; Arrhenius Law; Zeolite Y; Molecular Dynamics |
| ID Code: | 55822 |
| Deposited On: | 19 Aug 2011 05:44 |
| Last Modified: | 19 Aug 2011 05:44 |
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