Steroid hormones. Part XVI. Some organometallic and 3-deoxysteroids

Birch, A. J. ; Cross, P. E. ; Connor, D. T. ; Subba Rao, G. S. R. (1966) Steroid hormones. Part XVI. Some organometallic and 3-deoxysteroids Journal of the Chemical Society C: Organic . pp. 54-56. ISSN 0022-4952

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1966...

Related URL: http://dx.doi.org/10.1039/J39660000054

Abstract

Some derivatives of steroids having the 3-methoxy-2,5(10)-diene structure in ring-A reacted with chromium, molybdenum, or tungsten carbonyls, to give the metal tricarbonyl adducts of the ring-A-aromatic 3-deoxy-steroids. The adducts can be decomposed to give the parent compounds. Oestrone methyl ether gives crystalline chromium tricarbonyl and molybdenum tricarbonyl adducts.

Item Type:Article
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ID Code:55747
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