Synthesis based on cyclohexadienes: Part 4. Novel synthesis of the 6-aryl-2,4-dimethoxybenzoates. Alternariol and methyl trimethylaltenusin

Kanakam, Charles C. ; Mani, N. S. ; Subba Rao, G. S. R. (1990) Synthesis based on cyclohexadienes: Part 4. Novel synthesis of the 6-aryl-2,4-dimethoxybenzoates. Alternariol and methyl trimethylaltenusin Journal of the Chemical Society, Perkin Transactions 1 (8). pp. 2233-2237. ISSN 1472-7781

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1990...

Related URL: http://dx.doi.org/10.1039/P19900002233

Abstract

A novel method for the preparation of 6-aryl-2,4-dimethoxybenzoic acids involving the Alder-Rickert reaction of 1,5-dimethoxycyclohexa-1,4-dienes and arylpropiolic esters is described. This strategy has been extended to the synthesis of the mould metabolite alternariol and methyl trimethylaltenusin.

Item Type:Article
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