Total synthesis of the novel sesquiterpenes of Eremophila georgei Diels

Selvakumar, Natesan ; Subba Rao, G. S. R. (1994) Total synthesis of the novel sesquiterpenes of Eremophila georgei Diels Journal of the Chemical Society, Chemical Communications (11). pp. 1303-1304. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1994...

Related URL: http://dx.doi.org/10.1039/C39940001303

Abstract

The first stereoselective total synthesis of the natural sesquiterpenes 4 and 5, having the tricyclo[6.2.1.01,5]undecane skeleton with a bridgehead methyl group, is reported via the intermediate 9, which was obtained by the acid catalysed rearrangement of the alcohols 7 and 8.

Item Type:Article
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