Subba Rao, G. S. R. ; Vijaya Bhaskar, K. (1993) Synthesis based on cyclohexadienes. Part 9. Total synthesis of (±)-seychellene Journal of the Chemical Society, Perkin Transactions 1 (22). pp. 2813-2816. ISSN 1472-7781
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1993...
Related URL: http://dx.doi.org/10.1039/P19930002813
Abstract
A new strategy for the total synthesis of (±)-seychellene 1 is described. The key step is an intramolecular Michael addition involving a 6-exo cyclisation with a vinyl radical derived from the acetylenic compound 11, obtained from the bicyclo[2.2.2]octene adduct 5 to the tricyclic intermediates 14 and 15.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 55736 |
| Deposited On: | 19 Aug 2011 03:28 |
| Last Modified: | 19 Aug 2011 03:28 |
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