Synthesis based on cyclohexadienes. Part 17. Total synthesis of the sesquiterpenes of Eremophila georgei diels

Selvakumar, Natesan ; Janaki, Seenivasaga N. ; Pramod, Kakumanu ; Subba Rao, G. S. R. (1995) Synthesis based on cyclohexadienes. Part 17. Total synthesis of the sesquiterpenes of Eremophila georgei diels Journal of the Chemical Society, Perkin Transactions 1 (7). pp. 839-846. ISSN 1472-7781

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1995...

Related URL: http://dx.doi.org/10.1039/P19950000839

Abstract

The first stereoselective total synthesis of the novel sesquiterpenes 1 and 2 is described. The preparation of the key intermediate 27 involved a rearrangement of a bicyclo[3.2.1]octane framework to an isomeric bicyclo[3.2.1]octene skeleton via a bicyclo[2.2.2]octane derivative.

Item Type:Article
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ID Code:55732
Deposited On:19 Aug 2011 03:35
Last Modified:19 Aug 2011 03:35

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