Vinyl radical induced Michael additions: total synthesis of (−)-seychellene

Vijaya Bhaskar, K. ; Subba Rao, G. S. R. (1989) Vinyl radical induced Michael additions: total synthesis of (−)-seychellene Tetrahedron Letters, 30 (2). pp. 225-228. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)95166-9

Abstract

A new strategy for the total synthesis of (±)-seychellene which involves (i) a regiospecific construction of a bicyclo(2.2.2)octene moiety having a methyl group at the bridgehead and (ii) a vinyl radical induced intramolecular Michael addition is described.

Item Type:Article
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ID Code:55718
Deposited On:19 Aug 2011 03:24
Last Modified:19 Aug 2011 03:24

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