John Biju, P. ; Subba Rao, G. S. R. (1999) Aromatics to polyquinanes: a general method for the construction of tricyclo[6.3.0.04,8]-and tricyclo[6.3.0.02,6]undecanes Tetrahedron Letters, 40 (52). pp. 9379-9382. ISSN 0040-4039
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4039(99)02026-2
Abstract
The conversion of aromatic compounds to linear and angular triquinanes is described and involves a 5-exo-trig-allyl radical cyclization as the key reaction for constructing the strained ketones 9 and 18, which are then transformed into the quinanes 12 and 23, respectively. Novel methodology for the construction of angular and linear triquinane carbon frameworks is described, which involves a 5-exo-trig-allyl radical cyclization as one of the key reactions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 55707 |
| Deposited On: | 19 Aug 2011 03:35 |
| Last Modified: | 19 Aug 2011 03:35 |
Repository Staff Only: item control page
