A new strategy for the synthesis of spiro[4,5]decanes: a formal synthesis of acorone

John Biju, P. ; Subba Rao, G. S. R. (1999) A new strategy for the synthesis of spiro[4,5]decanes: a formal synthesis of acorone Tetrahedron Letters, 40 (12). pp. 2405-2406. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(99)00114-8

Abstract

A new strategy for the construction of spiro[4,5]decanes is described and involves a bridgehead substitution of a methoxyl group in 6 by a methyl group, followed by an oxidative cleavage resulting in a stereogenic spirocentre which culminated in the formal synthesis of acoron.

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ID Code:55692
Deposited On:19 Aug 2011 03:35
Last Modified:19 Aug 2011 03:35

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