Nonradiative dissociative electron capture by molecular ions

Warke, Chindhu S. (1966) Nonradiative dissociative electron capture by molecular ions Physical Review Online Archive, 144 (1). pp. 120-126. ISSN 0031-899X

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Official URL: http://prola.aps.org/abstract/PR/v144/i1/p120_1

Related URL: http://dx.doi.org/10.1103/PhysRev.144.120

Abstract

The rate of dissociative electron capture by heavy molecular ions is developed in the semiclassical formalism. The quantum treatment of the rate coefficient is also outlined. In the case of O2+, N2+, and He2+ the calculated rate coefficients are 1.14×10-7, 2.0×10-7, and 2.1×10-8 cm3/sec, respectively, at 300°K, as compared with the experimental values (1.7±1)×10-7 and (2.8±0.5)×10-7, and the upper limit 4.0×10-9 cm3/sec, respectively.

Item Type:Article
Source:Copyright of this article belongs to The American Physical Society.
ID Code:55625
Deposited On:18 Aug 2011 15:11
Last Modified:18 Aug 2011 15:11

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