Kaliappan, Krishna ; Subba Rao, G. S. R. (1997) Synthesis based on cyclohexadienes. Part 23. Total synthesis of 5-epi-pupukean-2-one Journal of the Chemical Society, Perkin Transactions 1 (22). pp. 3387-3392. ISSN 1472-7781
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1997...
Related URL: http://dx.doi.org/10.1039/A704312K
Abstract
A new strategy for the construction of the isotwistane skeleton is reported from easily available cyclohexadienes which involves stereoselective alkylation of a bicyclooctenone derivative and a decarboxylative 5-exo-trig radical cyclisation as the key steps in the total synthesis of 5-epi-pupukean-2-one.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 55586 |
| Deposited On: | 18 Aug 2011 11:25 |
| Last Modified: | 18 May 2016 07:48 |
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