Generation and reactivity of singlet oxygen within zeolites: remarkable control of hydroperoxidation of alkenes

Robbins, Rebecca J. ; Ramamurthy, V. (1997) Generation and reactivity of singlet oxygen within zeolites: remarkable control of hydroperoxidation of alkenes Chemical Communications (11). pp. 1071-1072. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1997...

Related URL: http://dx.doi.org/10.1039/A700977A

Abstract

A highly selective oxidation of alkenes included within a Y zeolite is achieved by generating singlet oxygen via excitation of a monomeric dye exchanged within a zeolite; conformational control brought forth by the medium is suggested to be responsible for the observed remarkable selectivity.

Item Type:Article
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ID Code:55501
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Last Modified:18 Aug 2011 11:42

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