Enhanced enantio- and diastereoselectivities via confinement: photorearrangement of 2,4-cyclohexadienones included in zeolites

Uppili, Sundararajan ; Ramamurthy, V. (2001) Enhanced enantio- and diastereoselectivities via confinement: photorearrangement of 2,4-cyclohexadienones included in zeolites Organic Letters, 4 (1). pp. 87-90. ISSN 1523-7060

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol010245w

Related URL: http://dx.doi.org/10.1021/ol010245w

Abstract

Employing zeolite as the reaction medium, it is possible to change the enantio (from achiral dienones) and diastereo (from chiral dienones) selectivities during the oxa-di-Π-methane rearrangement of 2,4-cyclohexadienones.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:55498
Deposited On:18 Aug 2011 11:43
Last Modified:18 Aug 2011 11:43

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