Control of enantioselectivity in the photochemical conversion of α-oxoamides into β-lactam derivatives

Natarajan, Arunkumar ; Wang, Keyan ; Ramamurthy, V. ; Scheffer, John R. ; Patrick, Brian (2002) Control of enantioselectivity in the photochemical conversion of α-oxoamides into β-lactam derivatives Organic Letters, 4 (9). pp. 1443-1446. ISSN 1523-7060

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol025700i

Related URL: http://dx.doi.org/10.1021/ol025700i

Abstract

Several approaches to asymmetric induction in the α-oxoamide (1) to β-lactam (2) photorearrangement are described. Best results are obtained via irradiation of ionic and covalent chiral auxiliary-containing reactants in the crystalline state and in the interior supercages of zeolites.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:55495
Deposited On:18 Aug 2011 11:45
Last Modified:18 Aug 2011 11:45

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