Shailaja, J. ; Ponchot, Keith J. ; Ramamurthy, V. (2000) Enantioselective photoreduction of arylalkyl ketones via restricting the reaction to chirally modified zeolite cages Organic Letters, 2 (7). pp. 937-940. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol000018e
Related URL: http://dx.doi.org/10.1021/ol000018e
Abstract
Obtaining a high enantiomeric excess during a photoreaction within a zeolite is hampered by the statistical distribution of reactant and chiral inductor molecules within the cages of a zeolite. By restricting the photoreactions to only those cages that contain both the reactant and a chiral inductor, one should be able to avoid reactions that yield racemic products. This approach is illustrated with the photoreduction of an arylalkyl ketone by a chiral inductor with an amino group.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 55489 |
| Deposited On: | 18 Aug 2011 11:43 |
| Last Modified: | 18 Aug 2011 11:43 |
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